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Silicone resin, scientifically known as polysiloxane resin or simply silicone resin, exhibits a highly cross-linked network structure of polyorganosiloxanes. It combines the dual characteristics of organic resins and inorganic materials, demonstrating unique physicochemical properties. The synthesis of silicone resin typically involves methyltrichlorosilane, dimethyldichlorosilane, phenyltrichlorosilane, and other chlorosilane mixtures as raw materials, undergoing hydrolysis and condensation reactions in the presence of organic solvents.
Silicone resin boasts exceptional thermal oxidation stability, with a weight loss of only 2% to 8% after heating at 250°C for 24 hours. Additionally, it possesses outstanding electrical insulation properties, maintaining good insulation performance across a wide range of temperatures and frequencies. These properties make silicone resin a crucial material in the electronics, textile, construction, and medical industries.
Silicone resin's weatherability is superior to that of common organic resins, with minimal yellowing even under intense ultraviolet radiation. It also exhibits resistance to chemicals, cold, radiation, flame retardancy, salt spray, mold, water repellency, and anti-stick/release properties. Consequently, silicone resin is widely used as high-temperature and low-temperature insulation varnishes, heat-resistant coatings, weather-resistant coatings, ablation-resistant coatings, and electrical insulation molding compounds that can withstand high and low temperatures.
In the electronics industry, silicone resin is primarily used as insulation varnish for impregnating coils in motors and transformers, as well as for manufacturing electrical insulation windings. In the construction sector, it serves as waterproof and moisture-proof coatings and adhesives. In the medical field, silicone resin is utilized in medical devices and implants due to its biocompatibility and stability.
Furthermore, silicone resin can be modified to enhance its properties. For instance, fluorination improves solvent resistance and oil repellency. Copolymerization with polyester, epoxy, or phenolic resins can yield high-temperature resistance and excellent mechanical properties.
The diverse types and extensive applications of silicone resin place it in a prominent position in the chemical industry. In the future, with technological advancements and increasing environmental protection requirements, silicone resin's properties will further improve, and its application fields will continue to expand.
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